• MOLECULAR AND INTERMOLECULAR BONDS
Intermolecular means the bonds outside molecules
- Intramolecular means bonds inside molecules
• Polarity is the result of intermolecular bonds
• Most bonds are electrostatic:
1. LONDON DISPURSION FORCE (L.D.F)
- Experienced by all molecules
- Result of electrons pushing on each other
- Weakest of all forces
- As the number of electrons increase L.D.F increases
- Comparison between the atoms Aluminum and Argon
Q:Which molecule will have a longer l.d.f?
A: Argon because it’s got more electrons. Which ever has more electrons experiences a longer LDF
- As the number of electrons increase L.D.F increases.
2. Dipole- Dipole
- Dipoles are partial separation of charges
- L.D.F is a type of temporary dipole
- Why is it a temporary dipole? Because electrons are always moving. Electrons always moving they don’t necessarily have to be in the same place.
- Some molecules have a permanent dipole
- These are polar molecules
- Polarity is determined by electrons affinity (how much an atom wants electrons)
- Electrons affinity is called electronegativity
- Electronegativity is highest on the top right and lowest on the bottom left

- Electronegativity is highest on the top right and lowest on the bottom left.
- A bond between two atoms/molecules with different electronegativities results in a dipole-dipole bond.
• Whats a dipole dipole strength between the two molecules Cl -Cl? None! Because none of them are polar
• Polar= dipole dipole
EXAMPLES: which bonds will result in a dipole-dipole force?
1.H-Clyes
2. O-Hyes
3. F-F No
4. O-Cl yes
5. I-Br yes
Are the following compounds polar or nonpolar?
1. CHCl3polar
2. 2. BI2Brpolar
3. C2H4non polar
4. C2H2Cl2non polar
DIPOLE DIPOLE FORCES ARE WEAK VERSIONS OF IONIC BONDS
COMPOUND Boiling Point Number of electrons
N2 -196 degrees celcius 14
O2 -183 16
NO -152 15
ICL 97 70
Br2 59 70
homework: questions 1 & 2 on worksheet
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